
What is shelf life?
Shelf life of any product is the time
within which it should be consumed.
Within that time, if the product is properly handled, it is
not expected to
significantly change from the condition in which it left its
manufacturer; it should conform to the information on its
original label, including its description,
indications, and methods of use and storage.
Proper handling is essential
to having a product achieve its expected shelf life:
if it is meant to be protected from heat or light but that
protection is not provided, the product will degrade more
quickly and may
become unusable or unsafe within its predicted shelf life.
When does shelf life begin?
There are several possible starting
points for reckoning a product's age. For manufacturers, the
manufacturing date is probably the starting point.
For any item which consists of more
than one raw ingredient, it is also important to consider that
each ingredient which was used to manufacture it also has its
own certain shelf life. Similar products can be made with old or new ingredients,
and the age of the ingredients may have some or no effect on the shelf life
of the finished product; information about the ages of components may be of
interest to consumers for aesthetic reasons, but it is unlikely to be provided
other than in generalities such as "fresh cream" or "aged cheese".
How is shelf life indicated on a label?
There are several methods of indicating
shelf life. Sometimes a date is specified; other times
a usage period, such as "use or discard within two weeks after
opening" is specified.
Many labels include a date, but this
is only meaningful information if the date is correctly interpreted.
Some labels show the date the item was manufactured.
This makes it possible for the consumer to know
how long the product has been on
the shelf before purchasing it. This method is used for products
with a relatively long shelf life where there is
no concern about the product going bad for a long
time or at all; dry foods such
as grains, powdered milk, and packaged sugar or salt are good
candidates for this approach. The
problem with marking a package with its date of manufacture
is that consumers are unlikely to know how to estimate the
usable time remaining for
the product,
so the only use they can make of this number is to compare
the manufacturing dates for every item on the shelf, searching
for the youngest (most recently manufactured) one.
Another method is for the manufacturer
to estimate an expiration date for the product, whereby the consumer
knows how much time
is left to use the product in the future but has no indication
as to how far in the past the product was
manufactured, nor how long it may have been sitting on a shelf
in a store.
Some labels will indicate how long a
product can be used after opening. This method
is good for products which normally have a long
shelf life while their packaging remains sealed, but a relatively
short
life after the seal is broken: canned food
and cosmeceuticals are likely to be in this category.
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In the European Union, cosmetics
are typically marked with a period-after-opening (PAO)
symbol to show how many months after opening a product can
be used "without any harm to the consumer". It's
important to note that the claim here is that the
cosmetic has not become dangerous, not that
it has
remained beneficial. In
part, this is due to the definition of cosmetics as inactive:
if they never could do anything, there is no reason to label
them as if at a certain point their activity degrades. It's
also consistent with the way fresh foods are handled, in that
a vegetable that has become a bit soft or slightly brown is
perfectly edible
for a long period after it has lost some of its visual attractiveness;
turn it into juice or soup, and it is enjoyable long after it
has ceased to be beautiful. For botanical-rich cosmeceuticals,
with a large portion of their ingredients subject to degrading
in the ways plant material naturally degrades (changing color
and texture, primarily), thinking about shelf life in this way
can be particularly
valid. |
"Best by" dates
also acknowledge the complexity of predicting how long a product
remains usable. A "best by"
date does not report a past milestone (manufacture date) and
rely on the consumer to calculate whether excessive time has
passed between that date and today's date. Nor does it make
an absolute
prediction about the future (expiration date), as if environmental
factors such as excellent or inadequate storage could not extend
or shorten the product's usable life. A "best by" date suggests
that some non-specific quality of the item, something available
when it is "best", degrades in a predictable-enough way that
it may no longer be "best" after a time; it remains up to the
consumer to decide whether a product is still "good" after it
has ceased to be "best".
A "sell by" date
is even more vague as to a product's actual age or its remaining
useful life, suggesting only a time by which the item
should be relocated
from a shelf
in
the store
to a
shelf in the consumer's home. This can be useful information
within a store as a means of distinguishing between last season's
model and this season's new-and-improved model (perhaps because
a buy-back guarantee will expire, or for some other administrative
reason), but it is not meant to advise a consumer as to when
a product
can no longer be safely
consumed.
For cosmetics distributed in the United
States, the FDA's Cosmetic
Labeling Manual does not require
any indication of shelf life although it does require that the
label identifiies the name and intended use of the product,
names its manufacturer or distributor, specifies the ingredients
and the quantity of finished material in the package, and provides
any necessary warnings or directions. For other products
such as drugs and nutritional supplements,
product labels or inserts must include additional information
as specified in the regulations for those products. Label space
is tight, especially on the small packages often used for cosmetics,
so
manufacturers are unlikely to squeeze
in anything that is not
absolutely required.
How is shelf life
estimated?
Shelf life is estimated by the manufacturer,
possibly with the assistance of external laboratories which specialize
in product stability testing. The natural method of estimating
shelf life is to use the product in the way it is expected to be
used by the consumer and observe when it starts to go bad, but
this is practical only when it is expected to go bad within a short
period.
Because it can sometimes take years
for a product to break down, accelerated stability testing shortens
the testing period by exposing a product to extreme stress: for
example, material can be exposed to high heat for a short period
rather than low heat for a long period. Of course, short-term exposure
to extreme stress sometimes results in altering a product so that
what is being tested has little resemblance to what consumers will
actually use. Accelerated stability testing is most likely to be
valid for materials that are primarily solid, such as steel construction
beams or rubber automobile tires; it is least likely to be valid
for materials such as foods and cosmetics, with contents naturally
high in liquids that may respond to high heat by becoming cooked
rather than by demonstrating their normal aging processes.
What happens after shelf life ends?
Entropy increases: unprotected
from the laws of physics, any complex structure tends to break
down with the passage of time. After a product
is manufactured, it begins to decay; the goal is to control (or
at least predict)
the rate of decay
to allow a reasonable time for the intended use of the product.
For different products, reasonable use time is different, ranging
from a few days for fresh fruit
to many years for canned fruit.
As products age, they can oxidize;
anti-oxidants have been
used as preservatives for
a very long time to slow down the rate of oxidation.
As oils age and oxidize they become rancid,
acquiring a strong and pungent smell. Many ingredients turn dark
brown as they
age, though for some ingredients that is their
natural color and not an indication of
oxidation and aging.
Preservatives, like other ingredients,
have their own aging processes and do not work indefinitely:
as time passes, preservatives lose their efficacy in fighting
against proliferation of bacteria or fungi and the
product can become
contaminated.
Many cosmetics are formulated as emulsions,
with naturally-separate oil and water phases combined
by chemical or physical means. Separation can be a sign that
an emulsion is reaching the end
of its useful life,
though it is also true that phase separation can be an inherent
feature of a product and not a sign of breakdown.
Oxidation and loss of bacterial protection
are results of chemical decay.
Physical decay can be a sign of an aging
product, demonstrated by phase separation when
this is not an intended feature of
the product, such as when
oils separate from the emulsion phase as free oil and not as
part of the emulsion. Gravitational separation of emulsion particles
which float up or settle down depending on their relative densities
is not a sign of decay when emulsion droplets are intact. In
such cases the label will advise the consumer to "shake well
before use".
So, a product's shelf life is determined
by its chemical and physical shelf life which also depends on
supporting ingredients which can extend final shelf life.
At the end of its shelf life, a product
no longer meets the standards set for it by its manufacturer.
It should be discarded at this point. A medicine may become
unsafe to use. Food may lose some of its nutritional
value, and a cosmetic may lose some of its skin-protective
value; both may become rancid
or
bacteria-infested.
Are there any ways to increase shelf
life?
Yes; many choices in the processes of
formulating, manufacturing, packaging, storing, and using a
product contribute to extending or shortening its shelf life.
Not all of these can be predicted by the manufacturer; even
if a label indicates that a product's shelf life has not yet
ended, consumers must be responsible for their own safety by
making their own decisions about whether it should be used.
The human senses of taste and smell provide us with highly-evolved
tools for judging whether any material can be safely handled
or consumed; if you don't trust it, don't use it.
Ingredient selection determines
the outer limits of a formulation's shelf life. In addition
to ingredients included strictly for the purpose of extending
shelf life ("preservatives"), ingredients included for
other purposes can make important contributions. In cosmetics,
anti-oxidants
included to provide anti-aging benefits to the skin can provide
similar protective benefits to the skin care in which they are
formulated. Similarly, anti-fungal and anti-bacterial ingredients
intended to treat infections when a cream is applied
to the skin can also prevent the growth of contaminants within
the cream itself. Long-standing preservation methods for foods
rely on ingredients such as salt (for pickling) and sugar (for
jellies, jams, preserves, and candies) that prevent decay but
alter the texture and flavor of the main ingredient. Many low-quality
skincare products have extremely long shelf lives because they
consist
largely of
mineral oil or alcohol, neither of which are particularly good
for skin but both of which are highly resistant to contamination
and degradation. Mineral oil is the final stage of decay for
dinosaurs; it cannot degrade much more!
Temperature control is
usually an effective method of increasing shelf life. Refrigeration
can extend shelf life, especially for material in open containers,
because low temperatures impede chemical reactions and slow
the growth of some bacteria. Refrigeration provides only partial
protection from contamination: as most of us know from unpleasant
personal experience, even in a closed container inside a refrigerator,
mold will eventually grow. For some materials such as foods
and single
chemical ingredients, freezing can
also be helpful; however, freezing is damaging to for water-based
cosmetics
because, when they
are removed from the freezer, the process of thawing can cause
their emulsion to de-formulate. Because this is such a key factor,
many labels are marked with manufacturer's recommendations
about
temperature
control such as "Refrigerate after opening" or "Do not freeze"
or "Store in a cool, dry place"; if consumers
do not follow those instructions, manufacturers' estimates of
shelf life become invalid.
Protection from light is
also often effective, which is why many cosmeceuticals,
vitamins, and food products are packaged in opaque rather
than clear
containers.
Protection from air,
which is the primary oxidizer and also carries bacteria,
mold, dust, and water, is also essential. Keeping a container
tightly closed when it is not in use,
and not opening a new container at all until it is
ready for use, are simple steps that are completely under
consumer control.
For manufacturers, choice of packaging
is the most important method of protecting a product from
air.
To help with this, "airless packaging" is sometimes
used: as
the skincare product is dispensed,
an inner chamber
pushes the remaining material into a smaller and smaller
area to protect it from exposure to the air that would
otherwise fill the "empty" space within the container.
Use of such packaging can be a high-cost option, but
the same philosophy can be followed by using some lower-cost
approaches.
For example, skincare should be
packaged in
a container no larger than is necessary for its contents;
something as simple as packaging 2 ounces of serum
in a 3-ounce bottle can cause the product to decay more
rapidly than it would in a properly-sized container,
free of contaminating
air. For low-thickness serums and lotions, using a
pump or spray to push material out of the container, rather
than allowing
fingers and air (both possibly contaminated) to enter
the container and extract material, is also a way
of
using packaging to improve a product's protection
from air.
Packaging into single-application
ampules or "ketchup packets" also
addresses
this: the
packaging is destroyed at the first and only moment
the product within
is exposed
to the air, so there is no possibility of re-closing
the package with air inside. |
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After any product is unsealed, it should
be used up quickly. When a container is opened for a quick sample
then
set aside for a long period, the product inside will age rapidly
when compared to the same material in a container that has remained
sealed during the same time. When you start using a product,
it is least likely to be wasted if you use it up continously
and without large gaps between uses.
Protection from water is
also important, for some of the same reasons as protection from
air. Also, water dilutes preservatives and supports the growth of
bacteria and mold, which is why, when a container
becomes
partially empty
and
a consumer adds water to "stretch" the remaining material, the
shelf life of this new, diluted material is greatly reduced
from that of the original formulation.
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| Refrigerated for 3
months in a flexible plastic container, cooked shredded
carrots are mold-free where the plastic lid was pressed
into direct contact with the carrots but mold-infested where
pockets of air exist between the carrots and the lid. |
A side view of the
same container shows that mold has spread downward into
loosely-packed areas where carrots are interrupted
by air pockets. |
Formulators can influence potential
shelf life by choosing the right ingredients, as packagers
can make an impact by using approriate packaging. Manufacturers
can provide key help to consumers by providing clear instructions
about how to store and use the product. Consumers can influence actual
shelf life by
keeping containers closed, following manufacturers' storage
instructions, and using their own good judgement about protecting
materials from damage and contamination.